Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-07-05 , DOI: 10.1016/j.cplett.2018.07.006 Ping Xue , Jing Shi , Xulong Cao , Shiling Yuan
Due to small shear viscosity of supercritical carbon dioxide, oil drilling leads to viscous fingering. Addition of polymer as thickener in supercritical CO2 has been used for improving the sweep efficiency of flooding. The simulated shear viscosity of supercritical CO2 systems increased with the addition of the polymer. The groups of the polymer have different ability to bind the supercritical CO2 molecules. The binding effect can mainly be attributed to space grid structure of polymer to reduce movement of CO2 molecules, in which the van der Waals interaction was the main constraint interaction.
中文翻译:
超临界CO 2增稠剂增稠机理的分子动力学模拟
由于超临界二氧化碳的剪切粘度小,石油钻探会导致粘性指法。在超临界CO 2中添加聚合物作为增稠剂已被用于提高驱油的波及效率。超临界CO 2系统的模拟剪切粘度随聚合物的添加而增加。聚合物的基团具有不同的结合超临界CO 2分子的能力。结合作用主要归因于聚合物的空间网格结构以减少CO 2分子的运动,其中范德华相互作用是主要的约束相互作用。