Schiff-base coordination complexes with plutonium(iv) and cerium(iv)†,Chemical Communications

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Schiff-base coordination complexes with plutonium(iv) and cerium(iv)†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-07-06 00:00:00 , DOI: 10.1039/c8cc03571g
Bonnie E. Klamm _{1,

2,

3,

4} , Cory J. Windorff _{1,

2,

3,

4} , Matthew L. Marsh _{1,

2,

3,

4} , David S. Meeker _{1,

2,

3,

4} , Thomas E. Albrecht-Schmitt _{1,

2,

3,

4}

Affiliation

PuL₂ and CeL₂ (L = N,N′-bis[(4,4′-diethylamino)salicylidene]-1,2-phenylenediamine) have been synthesized, and characterized by single crystal X-ray diffraction, UV/vis/NIR spectroscopy, and cyclic voltammetry. These studies reveal the enhanced stabilization of Pu(IV) versus Ce(IV) with this Schiff base, and quasi-reversible redox behaviour only with the plutonium complex.

中文翻译：

含iff（iv）和铈（iv）的席夫碱配位化合物†

合成了PuL ₂和CeL ₂（L = N，N'-双[（4,4'-二乙基氨基）水杨基] -1,2-苯二胺），并通过单晶X射线衍射，UV / vis /近红外光谱和循环伏安法。这些研究揭示浦（的增强稳定IV）相对于铈（IV）与该席夫碱，和仅与钚复杂准可逆的氧化还原行为。

更新日期：2018-07-06

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