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Remote activation of nanoparticulate biomimetic activity by light triggered pH-jump†‡
Chemical Communications ( IF 4.9 ) Pub Date : 2018-07-05 00:00:00 , DOI: 10.1039/c8cc04279a
Xiaopei Wang 1, 2, 3, 4, 5 , Ao Gong 1, 2, 3, 4, 5 , Wenhao Luo 1, 2, 3, 4, 5 , Haiqing Wang 1, 2, 3, 4, 5 , Changxu Lin 1, 2, 3, 4, 5 , Xiang Yang Liu 1, 2, 3, 4, 5 , Youhui Lin 1, 2, 3, 4, 5
Affiliation  

Herein, we report a facile, efficient and versatile method for the photo-regulation of pH-dependent activities of artificial enzymes by incorporating flash photolysis reagents. Under light excitation, a persistent pH shift is achieved by proton release from photosensitive 2-nitrobenzaldehyde. Following such change, the controlled activation of oxidase-like activity of nanoceria is successfully demonstrated.

中文翻译:

通过光触发的pH跳跃远程激活纳米颗粒的仿生活性

在本文中,我们报告了一种通过掺入快速光解剂对人造酶的pH依赖性活性进行光调节的简便,有效和通用的方法。在光激发下,通过从光敏的2-硝基苯甲醛释放质子来实现持久的pH转换。经过这样的改变,纳米氧化铈的氧化酶样活性的受控激活被成功证明。
更新日期:2018-07-05
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