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Remarkable enhancement of the photocatalytic activity of ZnO nanorod array by utilizing energy transfer between Eosin Y and Rose Bengal for visible light-driven hydrogen evolution
International Journal of Hydrogen Energy ( IF 7.2 ) Pub Date : 2018-07-07 , DOI: 10.1016/j.ijhydene.2018.06.113
Luwei He , Xiaomeng Dou , Xiangqing Li , Lixia Qin , Shi-Zhao Kang

In this work, we suggested that an efficient ZnO-based photocatalyst can be prepared utilizing energy transfer among organic dyes for visible light-driven hydrogen evolution. Followed this idea, a photocatalytic system containing Eosin Y, Rose Bengal, ZnO nanorod array and Pt was fabricated. Meanwhile, photocatalytic H2 evolution over the as-prepared photocatalytic system was explored. The results indicate that the visible photocatalytic activity of ZnO nanorod array can be obviously enhanced utilizing the energy transfer between Eosin Y and Rose Bengal. This photocatalytic system possesses high activity for visible light-driven H2 evolution. A rate of H2 evolution of approximate 0.52 L m−2 h−1 was achieved under optimal condition, which is 130% and 58% higher than those of the photocatalytic systems containing individual dye, respectively. The present results may reveal a new strategy for preparation of efficient visible photocatalyst.



中文翻译:

利用曙红Y和玫瑰红之间的能量转移显着增强了ZnO纳米棒阵列的光催化活性,从而促进了可见光驱动的氢气的释放

在这项工作中,我们建议可以利用有机染料之间的能量转移来制备有效的基于ZnO的光催化剂,用于可见光驱动的氢气释放。遵循此想法,制造了包含曙红Y,孟加拉红,ZnO纳米棒阵列和Pt的光催化系统。同时,探索了在所制备的光催化体系上光催化H 2的逸出。结果表明,利用曙红Y和玫瑰红之间的能量转移,可以明显提高ZnO纳米棒阵列的可见光催化活性。该光催化系统对于可见光驱动的H 2析出具有很高的活性。H 2的释放速率约为0.52 L m -2  h -1在最佳条件下获得了最佳光催化效果,分别比包含单个染料的光催化体系高出130%和58%。目前的结果可能揭示了一种制备高效可见光催化剂的新策略。

更新日期:2018-07-07
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