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Hierarchically responsive and photochromic imidazopyridazinium iodoargentate hybrid materials
Dyes and Pigments ( IF 4.5 ) Pub Date : 2018-07-04 , DOI: 10.1016/j.dyepig.2018.07.012 Shulin Lin , Pengfei Hao , Junju Shen , Yunlong Fu
中文翻译：
分层响应和光致变色咪唑并吡啶并叠氮碘杂酸盐材料
更新日期：2018-07-04
Dyes and Pigments ( IF 4.5 ) Pub Date : 2018-07-04 , DOI: 10.1016/j.dyepig.2018.07.012 Shulin Lin , Pengfei Hao , Junju Shen , Yunlong Fu
Three iodoargentate hybrids, [MIPDz]2[Ag2I4] (1), [AIPDz][Ag2I3] (2), and [MIPDz]2[Ag5I7] (3) (MIPDz+ = methylimidazopyridazinium, AIPDz+ = acetonylimidazopyridazinium), have been successfully synthesized, which exhibit improved photochromic properties and hierarchically responsive mechanism from optically inert response to photolysis of iodoargentates, until photoinduced intermolecular electron transfer with Ag particles as secondary electron donor.
中文翻译：
分层响应和光致变色咪唑并吡啶并叠氮碘杂酸盐材料
三种碘代古铜杂种[MIPDz] 2 [Ag 2 I 4 ]（1），[AIPDz] [Ag 2 I 3 ]（2）和[MIPDz] 2 [Ag 5 I 7 ]（3）（MIPDz + =甲基咪唑并吡啶并鎓，AIPDz + = acetonylimidazopyridazinium ），已经成功地合成，其显示出改进的光致变色特性和分层响应机制，从光学惰性到碘代精酸盐的光解反应，直到以Ag颗粒作为二次电子供体的光致分子间电子转移。
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