A simple and facile protocol for copper‐catalyzed regioselective C4 nitration and azidation of 1‐naphthylamines via remote C–H activation, using a pyridyl amide fragment as the removable directing group, has been developed. These reactions proceed under mild conditions without any additives, tolerate a wide variety of functional groups, and afford a wide range of products in good to excellent yields.

中文翻译：

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铜催化的区域选择性硝化和1-萘胺衍生物的远程C–H活化叠氮化

已经开发了一种简单而灵活的方案，该方案通过使用吡啶基酰胺片段作为可移动的导向基团，通过远程CH-H活化，通过铜催化的区域选择性C4硝化和1-萘胺的叠氮化。这些反应在温和的条件下进行，没有任何添加剂，可耐受各种官能团，并以良好或优异的收率提供了多种产品。