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A fluorometric paper-based sensor array for the discrimination of volatile organic compounds (VOCs) with novel salicylidene derivatives
Dyes and Pigments ( IF 4.5 ) Pub Date : 2018-06-30 , DOI: 10.1016/j.dyepig.2018.06.044
Thiti Jarangdet , Kornkanya Pratumyot , Kittiwat Srikittiwanna , Wijitar Dungchai , Withawat Mingvanish , Ittipon Techakriengkrai , Mongkol Sukwattanasinitt , Nakorn Niamnont

In this paper, novel salicylidene fluorescent sensors (1, 2, and 3) were successfully synthesized by the one pot condensation reaction and coated onto filter paper to produce fluorometric paper-based sensor array. The compound 1, 2, and 3 paper-based sensor arrays exhibited rapid fluorescent signal in response to exposure to 15 different VOC vapors. A smartphone was used as an alternative device to monitor the appearance of fluorescent signals. The images photographed using the smartphone camera were analyzed for RGB values by a conventional image-processing program. The ΔRGB data set (3 fluorophores × 15 VOC vapors × 4 repeats) from fluorescent images of 15 VOC vapors analysis have been statistically categorized by using principal component analysis (PCA) into 15 clusters with 100% discriminating accuracy. The proposed sensor array showed high potential as a portable electronic nose (e-nose) system for VOC vapors discrimination.



中文翻译:

一种基于荧光纸的传感器阵列,用于利用新型水杨基衍生物鉴别挥发性有机化合物(VOC)

在本文中,新亚水杨荧光传感器(12,和3)成功地被所述一个锅缩合反应合成,并涂覆在滤纸上,以产生荧光基于纸张的传感器阵列。的化合物12,3纸基传感器阵列响应暴露于15种不同的VOC蒸气而显示出快速的荧光信号。使用智能手机作为监视荧光信号外观的替代设备。使用智能手机相机拍摄的图像通过常规图像处理程序分析了RGB值。通过使用主成分分析(PCA)对15个VOC蒸气分析的荧光图像中的ΔRGB数据集(3个荧光团×15个VOC蒸气×4个重复)进行了统计分类,将其分类为15个簇,具有100%的辨别精度。所提出的传感器阵列作为用于VOC蒸气辨别的便携式电子鼻(电子鼻)系统具有很高的潜力。

更新日期:2018-06-30
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