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Activating basal plane in NiFe layered double hydroxide by Mn2+ doping for efficient and durable oxygen evolution reaction†
Nanoscale Horizons ( IF 9.7 ) Pub Date : 2018-06-27 00:00:00 , DOI: 10.1039/c8nh00121a
Daojin Zhou 1, 2, 3, 4, 5 , Zhao Cai 1, 2, 3, 4, 5 , Yin Jia 1, 2, 3, 4, 6 , Xuya Xiong 1, 2, 3, 4, 5 , Qixian Xie 1, 2, 3, 4, 5 , Shiyuan Wang 1, 2, 3, 4, 6 , Ying Zhang 5, 7, 8, 9 , Wen Liu 1, 2, 3, 4, 5 , Haohong Duan 10, 11, 12, 13, 14 , Xiaoming Sun 1, 2, 3, 4, 5
Affiliation  

Foreign metal ions with reducing ability were doped into NiFe layered double hydroxides (NiFe-LDHs) to activate the basal plane in NiFe-LDHs for oxygen evolution reaction (OER). Mn2+-Doped NiFe-LDH array electrode yields a low onset potential of 1.41 V and exhibits outstanding stability. The study herein illustrates a new dimension of electronic structure regulation and promises further optimization of highly efficient electrocatalysts.

中文翻译:

Mn 2+掺杂激活NiFe层状双氢氧化物中的基面,从而实现高效,持久的析氧反应

将具有还原能力的外来金属离子掺入NiFe层状双氢氧化物(NiFe-LDHs)中,以激活NiFe-LDHs中的基面进行氧释放反应(OER)。掺杂Mn 2+的NiFe-LDH阵列电极产生的起始电位低至1.41 V,并且具有出色的稳定性。本文的研究说明了电子结构调节的新领域,并有望进一步优化高效电催化剂。
更新日期:2018-06-27
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