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Intramolecular strong electronic coupling in a discretely H-aggregated phthalocyanine dimer connected with a rigid linker†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-28 00:00:00 , DOI: 10.1039/c8cc04335c Yasuyuki Yamada 1, 2, 3, 4, 5 , Katsuhiko Nawate 1, 2, 3, 4, 5 , Tomoaki Maeno 1, 2, 3, 4, 5 , Kentaro Tanaka 1, 2, 3, 4, 5
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-28 00:00:00 , DOI: 10.1039/c8cc04335c Yasuyuki Yamada 1, 2, 3, 4, 5 , Katsuhiko Nawate 1, 2, 3, 4, 5 , Tomoaki Maeno 1, 2, 3, 4, 5 , Kentaro Tanaka 1, 2, 3, 4, 5
Affiliation
Preparation of an accurate assembly of phthalocyanines is rather difficult because of the high aggregation property of phthalocyanines. In this study, a novel discrete phthalocyanine dimer was prepared in which the relative configuration of each component was tightly and accurately fixed in an H-aggregate form by a rigid U-shaped linker. Electrochemical measurements showed that there were strong intramolecular electronic interactions between the two phthalocyanines.
中文翻译:
分子内强电子耦合在与刚性接头连接的离散H聚集的酞菁二聚体中†
由于酞菁的高聚集性质,制备精确组装的酞菁是相当困难的。在这项研究中,制备了一种新颖的离散的酞菁二聚体,其中每个组分的相对构型通过刚性U形接头牢固而精确地固定为H聚集体形式。电化学测量表明,两种酞菁之间存在强烈的分子内电子相互作用。
更新日期:2018-06-28
中文翻译:
分子内强电子耦合在与刚性接头连接的离散H聚集的酞菁二聚体中†
由于酞菁的高聚集性质,制备精确组装的酞菁是相当困难的。在这项研究中,制备了一种新颖的离散的酞菁二聚体,其中每个组分的相对构型通过刚性U形接头牢固而精确地固定为H聚集体形式。电化学测量表明,两种酞菁之间存在强烈的分子内电子相互作用。