This review is an update on tris(trimethylsilyl)silane, TTMSS, in organic chemistry, focusing on the advancements of the past decade. The overview includes a wide range of chemical processes and synthetic strategies under different experimental conditions, including functional group insertion and transformations, as well as preparation of complex molecules, natural products, polymers, surfaces, and new materials. These results reveal how TTMSS has matured over the past 30 years, and they further establish its value as a free radical reagent with widespread academic and industrial applications.

中文翻译：

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（TMS）₃ SiH三十年：基于自由基的合成化学的里程碑

这篇综述是对有机化学中三（三甲基甲硅烷基）硅烷TTMSS的更新，重点是过去十年的进展。概述包括在不同实验条件下的各种化学过程和合成策略，包括官能团的插入和转化，以及复杂分子，天然产物，聚合物，表面和新材料的制备。这些结果揭示了TTMSS在过去30年中如何发展成熟，并进一步确立了其作为自由基试剂的价值，在学术和工业领域得到了广泛应用。