Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of cycloalkanol-substituted styrenes with N-acyloxyphthalimides and O-acyl oximes have been documented. These protocols provide efficient access to functionalized cyclic ketones, and feature mild conditions (i.e., visible light irradiation, redox neutral and room temperature), broad substrate scope and excellent functional group tolerance.

中文翻译：

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烯基环丁醇的光氧化还原促进的烷基自由基加成/ Semipinacol重排序列：快速获得环酮†

已有文献报道环烷醇取代的苯乙烯与N-酰氧基邻苯二甲酰亚胺和O-酰基肟的两个光催化串联烷基自由基加成/ semipinacol重排反应。这些协议可提供对功能化环酮的有效访问，并具有温和的条件（即可见光辐射，氧化还原中性和室温），广泛的底物范围和出色的官能团耐受性。