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Selective Catalytic Hydration of Alkynes in the Presence of Au‐Cavitands: A Study in Structure–Activity Relationships
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-08-17 , DOI: 10.1002/ejoc.201800948
Mami Inoue 1 , Katto Ugawa 1 , Tomoyuki Maruyama 1 , Tetsuo Iwasawa 1
Affiliation  

Supramolecular catalysis was investigated by comparative studies with corresponding model catalysts featuring weakened cage architecture and functionality. A diquinoxaline‐spanned resorcin[4]arene bearing Lewis acid and base components selectively catalyzed alkyne hydration, allowing us to investigate structure–activity relationships and to identify significant skeletons.
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中文翻译:

Au-Cavitands存在下炔烃的选择性催化水合:结构与活性关系的研究

通过比较研究对超分子催化进行了研究,并与相应的模型催化剂进行了比较,这些模型催化剂的骨架结构和功能均较弱。带有路易斯酸和碱成分的二喹喔啉间苯二酚[4]芳烃选择性催化炔烃水合,从而使我们能够研究结构与活性的关系并鉴定出重要的骨架。
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更新日期:2018-08-17
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