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Kinetic Resolution of α‐Hydroxy‐Substituted Oxime Ethers by Enantioselective Cu−H‐Catalyzed Si−O Coupling
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2018-06-21 , DOI: 10.1002/anie.201806828
Xichang Dong 1 , Yuji Kita 1 , Martin Oestreich 1
Affiliation  

A quick solution to the kinetic resolution of oxime ethers by asymmetric Cu−H‐catalyzed dehydrogenative silylation of hydroxy groups in the α‐position is described by Berlin‐based M. Oestreich and co‐workers in their Communication (DOI: 10.1002/anie.201802947). The cover picture is inspired by the modernist design movement Bauhaus and visualizes the chemical structures and the energy profile of the reaction in an abstract, yet meaningful way.


中文翻译:

对映选择性Cu-H-催化的Si-O偶联的α-羟基取代的肟醚的动力学拆分

柏林的M.Oestreich及其同事在其《通讯》中描述了一种通过不对称的CuH催化α位上的羟基的脱氢甲硅烷基化反应快速分解肟醚的方法(DOI:10.1002 / anie。 201802947)。封面图片受到现代主义设计运动包豪斯(Bauhaus)的启发,以一种抽象而有意义的方式形象化了反应的化学结构和能量分布。
更新日期:2018-06-22
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