Catalytic, metal-free alkylheteroarylation of alkenes via distal heteroaryl ipso-migration†,Chemical Communications

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Catalytic, metal-free alkylheteroarylation of alkenes via distal heteroaryl ipso-migration†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-18 00:00:00 , DOI: 10.1039/c8cc03911a
Yonghui He _{1,

2,

3,

4,

5} , Yaqi Wang _{1,

2,

3,

4,

5} , Jun Gao _{1,

2,

3,

4,

5} , Liang Zeng _{1,

2,

3,

4,

5} , Shusheng Li _{1,

2,

3,

4,

5} , Wei Wang _{1,

2,

3,

4,

5} , Xiaohui Zheng _{5,

6,

7} , Shengyong Zhang _{5,

8,

9} , Lijun Gu _{1,

2,

3,

4,

5} , Ganpeng Li _{1,

2,

3,

4,

5}

Affiliation

A new direct alkylheteroarylation of alkenes with simple alkylnitriles via distal heteroaryl ipso-migration has been accomplished under metal-free conditions, in which inexpensive alkylnitriles served as radical precursors, which together with ease of operation makes this process a very practical protocol.

中文翻译：

催化，烯烃的无金属alkylheteroarylation经由远端杂本位-migration †

用简单的烷基腈烯烃的新的直接alkylheteroarylation经由远端杂本位-migration已不含金属的条件下，在这种廉价的烷基腈担任自由基前体，其与操作方便一起使得该方法非常实用协议下实现的。

更新日期：2018-06-18

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