Central metal dependent modulation of induced-fit gas uptake in molecular porphyrin solids,Chemical Communications

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Central metal dependent modulation of induced-fit gas uptake in molecular porphyrin solids
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-16 , DOI: 10.1039/c8cc03646b
Hirotomo Nishihara _{1,

2,

3,

4} , Mao Ohwada _{1,

2,

3,

4} , Takuya Kamimura _{4,

5,

6,

7} , Masato Nishimura _{4,

5,

6,

7} , Hideki Tanaka _{4,

8,

9,

10} , Shotaro Hiraide _{4,

8,

9,

10} , Minoru T. Miyahara _{4,

8,

9,

10} , Katsuhiko Ariga _{4,

11,

12,

13,

14} , Qingmin Ji _{4,

11,

12,

13,

14} , Jun Maruyama _{4,

15,

16,

17} , Fumito Tani _{4,

5,

6,

7}

Affiliation

Institute of Multidisciplinary Research for Advanced Materials
Tohoku University
Sendai
Japan
Institute for Materials Chemistry and Engineering
Kyushu University
Fukuoka 819-0395
Department of Chemical Engineering
Kyoto University
Kyoto 615-8510
World Premier International (WPI) Research Center for Materials
Nanoarchitechtonics (MANA)
National Institute for Materials Science (NIMS)
Tsukuba
Research Division of Environmental Technology
Osaka Research Institute of Industrial Science and Technology
Osaka 536-8553

The induced-fit accommodation of a variety of gaseous molecules including non-polar molecules has been demonstrated in porphyrin-based supramolecular architectures for the first time. Moreover, the gas uptake behaviour can be modulated by changing the central cation of porphyrin.

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