The utilization of metalloporphyrin analogues as biomimetic oxidation catalysts is an evolutionary topic of research. Current environmental concerns have directed research in this field for the design, synthesis and application of heterogeneous catalysts, as well as avoiding the use of highly pollutant co‐oxidants and/or co‐catalysts. Herein, we review the last decade concerning the sole use of environmentally benign oxidant source hydrogen peroxide, in oxidation reactions catalyzed by metalloporphyrin analogues, both in homogeneous and heterogeneous conditions. We did not intend to create a comprehensive review; instead we highlight the most important and illustrative examples for this period. We emphasize the application of such catalysts on the oxidation reactions of many relevant substrates using heterogeneous metalloporphyrin based catalysts, specially using inorganic supports for more accessible reutilization protocols.

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过氧化氢和金属卟啉在氧化催化中的应用：新技术的老狗

金属卟啉类似物作为仿生氧化催化剂的利用是研究的一个发展主题。当前对环境的关注已指导着该领域中多相催化剂的设计，合成和应用研究，以及避免使用高污染的助氧化剂和/或助催化剂。在本文中，我们回顾了过去十年中有关在纯金属和非均质条件下金属卟啉类似物催化的氧化反应中仅使用环境友好型氧化剂源过氧化氢的情况。我们无意进行全面审查。相反，我们重点介绍了这一时期最重要和最具说明性的例子。我们强调在多相金属卟啉基催化剂对许多相关底物的氧化反应中应用这类催化剂，