We suggest that a family of Ni-based compounds, which contain [Ni₂M₂O]²⁻ (M = chalcogen) layers with an antiperovskite structure constructed by mixed-anion Ni complexes, NiM₄O₂, can be potential high temperature superconductors (high-T_c) upon doping or applying pressure. The layer structures have been formed in many other transitional metal compounds such as La₂B₂Se₂O₃ (B = Mn, Fe, Co). For the Ni-based compounds, we predict that the parental compounds host collinear antiferromagnetic states similar to those in iron-based high temperature superconductors. The electronic physics near Fermi energy is controlled by two $e_g$ d-orbitals with completely independent in-plane kinematics. We predict that the superconductivity in this family is characterized by strong competition between extended s-wave and d-wave pairing symmetries.

我们认为，含有 [Ni ₂ M ₂ O] ²⁻（M = 硫属元素）层的一族镍基化合物具有由混合阴离子 Ni 络合物 NiM ₄ O ₂构建的反钙钛矿结构，可能是潜在的高温掺杂或施加压力后的超导体（高温_C ） 。层结构已在许多其他过渡金属化合物中形成，例如 La ₂ B ₂ Se ₂ O ₃（B = 锰、铁、钴）。对于镍基化合物，我们预测母体化合物具有与铁基高温超导体相似的共线反铁磁态。费米能量附近的电子物理由两个控制${\mathrm{电子}}_G$ 具有完全独立的平面内运动学的d轨道。我们预测该族的超导性以扩展的 s波和d波配对对称性之间的强烈竞争为特征。