Metal bis(porphyrinato) double‐decker complexes have been used for the construction of functional molecules such as molecular machines and single‐molecule magnets. Here, switching of the azimuthal rotation angle of terbium double‐decker complexes by redox stimulation is presented. This could contribute not only to a better understanding of their structure–property relationship but also to the design of redox‐driven molecular machines such as those similar to a Ferris wheel. More information can be found in the Full Paper by Ken‐ichi Yamashita, Takuji Ogawa et al. on page 1692 in Issue 13, 2018 (DOI: 10.1002/asia.201800324).

中文翻译：

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前封面：卟啉大环的方位旋转引起Red（III）双（卟啉）双层配合物的氧化还原驱动对称性变化（亚洲化学杂志，J.13 / 2018）

金属双卟啉双层配合物已用于构建功能分子，例如分子机器和单分子磁体。在此，提出了通过氧化还原刺激来切换double双层配合物的方位角旋转角的方法。这不仅有助于更好地了解它们的结构与属性之间的关系，而且有助于氧化还原驱动的分子机器（例如类似于摩天轮的机器）的设计。有关更多信息，请参见山下贤一，小川隆司等的《全文》。就在第13期，2018页1692（：10.1002 / asia.201800324 DOI）。