Anion directing self-assembly of 2D and 3D water-stable silver(i) cation metal organic frameworks and their applications in real-time discriminating cysteine and DNA detection†,Journal of Materials Chemistry B

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Anion directing self-assembly of 2D and 3D water-stable silver(i) cation metal organic frameworks and their applications in real-time discriminating cysteine and DNA detection†
Journal of Materials Chemistry B ( IF 7 ) Pub Date : 2018-06-13 00:00:00 , DOI: 10.1039/c8tb01032c
Xin Rui Wang _{1,

2,

3,

4,

5} , Jing Du _{1,

2,

3,

4,

5} , Zhuo Huang _{1,

2,

3,

4,

5} , Kun Liu _{1,

2,

3,

4,

5} , Yuan Yuan Liu _{1,

2,

3,

4,

5} , Jian Zhong Huo _{1,

2,

3,

4,

5} , Zhong Yi Liu _{1,

2,

3,

4,

5} , Xiao Yu Dong _{1,

2,

3,

4,

5} , Li Li Chen _{1,

2,

3,

4,

5} , Bin Ding _{1,

2,

3,

4,

5}

Affiliation

Two water-stable silver(I) cation metal organic frameworks (MOFs), namely 2D MOF {[Ag(L)₂]BF₄}_n (1) and 3D MOF {[Ag₃(L)₃]·(H₂O)·(CF₃SO₃)₃}_n (2) (L = 1-(4-aminobenzyl)-1,2,4-triazole), have been prepared. 1 is the first example of a 2D MOF-based sensor for real-time discrimination of L- and D-cysteine from other amino acids through the quenching effect. Through deliberately tuning the nanoparticles of 2 under ultrasound conditions, these nanoparticles are, for the first time, successfully applied as an excellent DNA detecting platform.

中文翻译：

阴离子指导2D和3D耐水银（i）阳离子金属有机骨架的自组装及其在实时区分半胱氨酸和DNA检测中的应用†

两种水稳定性银（I）阳离子金属有机骨架（MOF），即2D MOF {[Ag（L）₂ ] BF ₄ } _n（1）和3D MOF {[Ag ₃（L）₃ ]·（H ₂制备了O）·（CF ₃ SO ₃）₃ } _n（2）（L ＝ 1-（4-氨基苄基）-1，2，4-三唑）。图1是用于实时识别L-和D的基于2D MOF的传感器的第一个示例-半胱氨酸通过其他氨基酸的淬灭作用。通过在超声条件下故意调节2的纳米粒子，这些纳米粒子首次成功地用作了出色的DNA检测平台。

更新日期：2018-06-13

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