One pot preparation of α-dithioacetal/α-diselenoacetal amides via a dual-C–S/C–Se bond formation and C–C bond cleavage cascade of 3-oxo-butanamides†‡,Organic Chemistry Frontiers

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One pot preparation of α-dithioacetal/α-diselenoacetal amides via a dual-C–S/C–Se bond formation and C–C bond cleavage cascade of 3-oxo-butanamides†‡
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2018-06-13 00:00:00 , DOI: 10.1039/c8qo00435h
Jiao-xia Zou _{1,

2,

3,

4} , Yong-qiang Wang _{1,

2,

3,

4} , Long-tao Huang _{1,

2,

3,

4} , Yi Jiang _{1,

2,

3,

4} , Jin-hong Chen _{1,

2,

3,

4} , Long-qing Zhu _{1,

2,

3,

4} , Yu-hang Yang _{1,

2,

3,

4} , Yi-yue Feng _{1,

2,

3,

4} , Xue Peng _{1,

2,

3,

4} , Zhen Wang _{1,

2,

3,

4,

5}

Affiliation

A new and practical approach to α-dithioacetal/α-diselenoacetal amides has been developed, combining sequential functionalization of amides and a C–C bond cleavage strategy. In this reaction, various α-dithioacetal/α-diselenoacetal amides from 3-oxo-butanamides were prepared in one step with good regioselectivity and functional group tolerance.

中文翻译：

一锅制备α-二硫缩醛/α-diselenoacetal酰胺通过的3-氧代- butanamides双C-S / C-Se键的形成和C-C键断裂级联†往最 ‡

已经开发出一种新的实用的α-二硫缩醛/α-二硒缩醛酰胺方法，该方法结合了酰胺的顺序功能化和CC键裂解策略。在该反应中，一步制得了3-氧代丁酰胺中的各种α-二硫缩醛/α-二硒缩醛酰胺，具有良好的区域选择性和官能团耐受性。

更新日期：2018-06-13

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