Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar–layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P₄). Our research may provide a new approach for the synthesis of various 2D materials.

中文翻译：

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在基于 MOF 的二维纳米反应器中合成二维磷材料†

二维（2D）材料的合成主要依赖于界面模板、层状晶体的剥离和表面活性剂的辅助。在这里，我们实现了二维纳米反应器中的另一种聚合策略。作为该策略的一种应用，在新的柱层金属有机骨架（MOF）内构建了一个二维纳米反应器，并在该纳米反应器中由白磷（P ₄）合成了一种中等稳定性的二维磷材料。我们的研究可能为各种二维材料的合成提供一种新方法。