Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice†,Chemical Communications

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Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-11 00:00:00 , DOI: 10.1039/c7cc09921e
Bianca Baldo _{1,

2,

3,

4,

5} , Francisco Rubio _{1,

2,

3,

4,

5} , Erwin Flores _{1,

2,

3,

4,

5} , Andres Vega _{1,

2,

3,

4,

5} , Nathalie Audebrand _{6,

7,

8} , Diego Venegas-Yazigi _{4,

5,

9,

10,

11} , Verónica Paredes-García _{1,

2,

3,

4,

5}

Affiliation

Here we report the first examples of 3d–4f compounds based on Ln^II cations. We have obtained a series of Ni₂[LnCl₆] isostructural compounds where Ln^II = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm [3 with combining macron]

m space group. Magnetic and optical characterization was also performed on this new class of compounds.

中文翻译：

Ni ₂ [LnCl ₆ ]（Ln = Eu ^II，Ce ^II，Gd ^II）：稳定在纯无机晶格中的第一批Ln ^II化合物†

在这里，我们报告基于Ln ^II阳离子的3d–4f化合物的第一个示例。我们获得了一系列Ni ₂ [LnCl ₆ ]同构化合物，其中Ln ^II = Ce 1，Eu 2和Gd 3，其特征是具有Fm [3与组合光子组合]