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Electrodepositing ultra-thin Ni(OH)2 amorphous film on Ni2P nanosheets array: an efficient strategy toward greatly enhanced alkaline hydrogen evolution reaction†
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2018-06-06 00:00:00 , DOI: 10.1039/c8nj01910j
Zhenhua Zhang 1, 2, 3, 4, 5 , Yao Jiang 1, 2, 3, 4, 5 , Xiangjiang Zheng 1, 2, 3, 4, 5 , Xuping Sun 5, 6, 7, 8 , Yingshu Guo 1, 2, 3, 4, 5
Affiliation  

The development of highly active noble-metal-free catalysts for alkaline hydrogen evolution reaction (HER) can greatly lower the cost of hydrogen economy and boost the utilization of clean and renewable energy. Herein, we report an interface-engineered nanostructure (Ni(OH)2–Ni2P/Ti) as a highly efficient HER catalyst. Impressively, the newly generated hybrid catalyst exhibits superior catalytic activity when compared to that of pristine Ni2P/Ti. It only requires overpotentials of 57 and 85 mV to afford current densities of 10 and 20 mA cm−2 in 1.0 M KOH, respectively, with its catalytic activity being retained for 24 h.

中文翻译:

在Ni 2 P纳米片阵列上 电沉积超薄Ni(OH)2非晶态膜:一种有效增强碱性氢释放反应的有效策略

开发用于碱性氢释放反应(HER)的高活性,不含贵金属的催化剂可以大大降低氢经济成本,并促进清洁和可再生能源的利用。在本文中,我们报告了一种界面工程纳米结构(Ni(OH)2 -Ni 2 P / Ti)作为高效HER催化剂。令人印象深刻的是,与原始Ni 2 P / Ti相比,新生成的杂化催化剂表现出优异的催化活性。它仅需要57和85 mV的超电势即可在1.0 M KOH中分别提供10和20 mA cm -2的电流密度,并且其催化活性保持24小时。
更新日期:2018-06-06
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