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Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability†
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2018-06-05 00:00:00 , DOI: 10.1039/c8qi00471d
Dong Chen 1, 2, 3, 4 , Pengfei Zhang 1, 2, 3, 4, 5 , Qianrong Fang 4, 6, 7, 8 , Shun Wan 5, 9, 10, 11 , Hui Li 4, 6, 7, 8 , Shize Yang 5, 9, 10, 11 , Caili Huang 5, 9, 10, 11 , Sheng Dai 5, 9, 10, 11, 12
Affiliation  

A simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m2 g−1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.

中文翻译:

配位支持的有机聚合物:具有较好稳定性的中孔无机有机材料

通过借鉴MOF和COF的化学思想,开发了一种简单而通用的策略,用于通过Al 3+和5-氨基-8-羟基喹啉与有机亚胺基或亚胺基的配位来合成配位支撑的有机聚合物(COP)基于酰亚胺的缩聚。具有高表面积(高达1123 m 2 g -1)和丰富的中孔(2.5 nm或14 nm)的COP浸泡在沸水中后具有良好的晶体和多孔结构。
更新日期:2018-06-05
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