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Measurement and Modelization of VLE for Butyl Acetate with Methanol, Ethanol, 1-Propanol, and 1-Butanol. Experimental Data at 0.15 MPa
Journal of Chemical & Engineering Data ( IF 2.6 ) Pub Date : 2018-06-04 , DOI: 10.1021/acs.jced.8b00182
Pedro Susial Badajoz 1 , Diego García-Vera 1 , José David González-Domínguez 1 , Patricia Herrera-Vega 1
Affiliation  

Vapor–liquid equilibrium at 0.15 MPa for binary mixtures of butyl acetate with methanol, ethanol, 1-propanol, and 1-butanol has been measured. The thermodynamic consistency was verified with the Redlich–Kister test, the Herington test, the direct Van Ness test, and the point-to-point test. Azeotropic data was found for the butyl acetate + 1-butanol binary system at 0.15 MPa. Modeling of binary systems was obtained by employing the group contribution models (ASOG and different versions of UNIFAC) and the perturbed chain-statistical associating fluid theory equation of state.

中文翻译:

用甲醇,乙醇,1-丙醇和1-丁醇对乙酸丁酯的VLE进行测量和建模。0.15 MPa下的实验数据

已测量了乙酸丁酯与甲醇,乙醇,1-丙醇和1-丁醇的二元混合物在0.15 MPa时的气液平衡。通过Redlich-Kister试验,Herington试验,直接Van Ness试验和点对点试验验证了热力学一致性。发现乙酸丁酯+ 1-丁醇二元体系在0.15 MPa下的共沸数据。通过使用组贡献模型(ASOG和UNIFAC的不同版本)和扰动链统计联合流体理论状态方程,获得了二元系统的模型。
更新日期:2018-06-05
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