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High-throughput CO2 capture for biogas purification using monoethanolamine in a microtube contactor
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-06-02 , DOI: 10.1016/j.jtice.2018.05.002
Nattee Akkarawatkhoosith , Amaraporn Kaewchada , Attasak Jaree

The utilization of biogas is somewhat limited by its composition especially CO2. The CO2 content in biogas can be substantially reduced via chemical absorption. In this work, the absorption performance of CO2 removal from biogas using aqueous monoethanolamine (MEA) in a T-type microchannel (0.5 × 0.5 × 60 mm3) was experimentally investigated. The effects of operating parameters including MEA-to-CO2 molar ratio, temperature, pressure, and flow rate of MEA solution were studied in terms of main and interaction effects via statistical analysis. Temperature and MEA-to-CO2 molar ratio showed relatively strong influence on both %absorption and the liquid-side volumetric mass transfer coefficient. A positive confounding effect between these two parameters was also present. Hence, high temperature and high molar ratio resulted in high performance CO2 removal from biogas. Methane purity of 90% was obtained with the molar ratio of 1.8 at 50 °C. The kLa of 517 s−1 was achieved at the MEA-to-CO2 molar ratio of 5:1, 50 °C, 2 bar, and 3 mL/min of the MEA solution. In addition, the absorption flux of CO2 in MEA solution, overall mass transfer coefficient, and kinetic rate constant were evaluated to interpret the experimental results.



中文翻译:

高通量CO 2捕集,用于在微管接触器中使用单乙醇胺净化沼气

沼气的利用在某种程度上受到其成分特别是CO 2的限制。沼气中的CO 2含量可通过化学吸收大大降低。在这项工作中,实验研究了使用T型微通道(0.5×0.5×60 mm 3)中的单乙醇胺水溶液(MEA)从沼气中去除CO 2的吸收性能。通过统计分析,从主效应和相互作用的角度研究了MEA -CO 2摩尔比,MEA溶液的温度,压力和流速等操作参数的影响。温度和MEA-to-CO 2摩尔比对%吸收和液体侧体积传质系数均显示相对强烈的影响。这两个参数之间也存在积极的混杂效应。因此,高温和高摩尔比导致从沼气中去除高性能的CO 2。在50℃下以1.8的摩尔比获得90%的甲烷纯度。在MEA溶液与CO 2的摩尔比为5:1、50°C,2 bar和3 mL / min的MEA溶液中,达到517 s -1k L a。另外,评估了MEA溶液中CO 2的吸收通量,总传质系数和动力学速率常数,以解释实验结果。

更新日期:2019-02-27
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