Spinterface engineering has shown quite important roles in organic spintronics as it can improve spin injection or extraction. In this study, 11,11,12,12‐tetracyanonaptho‐2,6‐quinodimethane (TNAP) is introduced as an interfacial layer for a prototype interface of Fe/TNAP. An element‐specific investigation of the electronic and magnetic structures of Fe/TNAP system by use of near edge X‐Ray absorption fine structure (NEXAFS) and X‐ray magnetic circular dichroism (XMCD) is reported. Strong hybridization between TNAP and Fe and induced magnetization of N atoms in TNAP molecule are observed. XMCD sum rule analysis demonstrates that the adsorption of TNAP reduces the spin moment of Fe by 12%. In addition, induced magnetization in N K‐edge of TNAP is also found with other commonly used ferromagnets in organic spintronics, such as La_0.7Sr_0.3MnO₃ and permalloy, which makes TNAP a very promising molecule for spinterface engineering in organic spintronics.

中文翻译：

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与用于有机自旋电子学的铁磁电极接触的11,11,12,12-四氰基萘-2-6，喹啉二甲烷

Spinterface工程在有机自旋电子学中已显示出非常重要的作用，因为它可以改善自旋注入或萃取。在这项研究中，引入11,11,12,12-四氰基萘-2,6-喹二甲烷（TNAP）作为Fe / TNAP原型界面的界面层。报告了通过使用近边缘X射线吸收精细结构（NEXAFS）和X射线磁圆二向色性（XMCD）对Fe / TNAP系统的电子和磁性结构进行的元素特定研究。观察到TNAP和Fe之间的强杂交以及TNAP分子中N原子的磁化。XMCD和规则分析表明，TNAP的吸附使Fe的自旋矩降低了12％。此外，还发现有机自旋电子学中的其他常用铁磁体（例如La）也能在TNAP的NK边缘中感应出磁化强度。_0.7 Sr _0.3 MnO ₃和坡莫合金，这使得TNAP成为有机自旋电子学中界面工程非常有前景的分子。