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Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-31 00:00:00 , DOI: 10.1039/c8cc03838d Shi-Qiang Wang 1, 2, 3, 4, 5 , Qing-Yuan Yang 1, 2, 3, 4, 5 , Soumya Mukherjee 1, 2, 3, 4, 5 , Daniel O’Nolan 1, 2, 3, 4, 5 , Ewa Patyk-Kaźmierczak 1, 2, 3, 4, 5 , Kai-Jie Chen 1, 2, 3, 4, 5 , Mohana Shivanna 1, 2, 3, 4, 5 , Claire Murray 6, 7, 8, 9 , Chiu C. Tang 6, 7, 8, 9 , Michael J. Zaworotko 1, 2, 3, 4, 5
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-31 00:00:00 , DOI: 10.1039/c8cc03838d Shi-Qiang Wang 1, 2, 3, 4, 5 , Qing-Yuan Yang 1, 2, 3, 4, 5 , Soumya Mukherjee 1, 2, 3, 4, 5 , Daniel O’Nolan 1, 2, 3, 4, 5 , Ewa Patyk-Kaźmierczak 1, 2, 3, 4, 5 , Kai-Jie Chen 1, 2, 3, 4, 5 , Mohana Shivanna 1, 2, 3, 4, 5 , Claire Murray 6, 7, 8, 9 , Chiu C. Tang 6, 7, 8, 9 , Michael J. Zaworotko 1, 2, 3, 4, 5
Affiliation
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A nonporous square lattice (sql) coordination network [Co(bipy)2(NCS)2]n (sql-1-Co-NCS) exhibits recyclable switching induced by CO2. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.
中文翻译：
方形晶格（sql）拓扑协调网络的无孔和多孔相之间的可循环切换†
无孔方格（sql）协调网络[Co（bipy）2（NCS）2 ] n（sql-1-Co-NCS）表现出由CO 2诱导的可循环转换。吸附等温线的阶跃具有适度的滞后，温度可控，并且饱和吸收是固定的。这种很少被观察到的切换为气体存储提供了超常的工作能力。
更新日期：2018-05-31
中文翻译：
方形晶格（sql）拓扑协调网络的无孔和多孔相之间的可循环切换†
无孔方格（sql）协调网络[Co（bipy）2（NCS）2 ] n（sql-1-Co-NCS）表现出由CO 2诱导的可循环转换。吸附等温线的阶跃具有适度的滞后，温度可控，并且饱和吸收是固定的。这种很少被观察到的切换为气体存储提供了超常的工作能力。
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