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A highly active and synergistic Pt/Mo2C/Al2O3 catalyst for water-gas shift reaction
Molecular Catalysis ( IF 4.6 ) Pub Date : 2018-05-29 , DOI: 10.1016/j.mcat.2018.05.025
Ahmed I. Osman , Jehad K. Abu-Dahrieh , Nikolay Cherkasov , Javier Fernandez-Garcia , David Walker , Richard I. Walton , David W. Rooney , Evgeny Rebrov

Catalysts consisting of Pt and Cu supported on Mo2C/η-Al2O3, Mo2C/γ-Al2O3 or Mo2C were prepared and used for the low-temperature water gas shift reaction (WGSR). The catalysts were characterized by elemental analysis, powder X-ray diffraction (XRD), temperature-programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The catalysts were studied in water gas shift reaction with a reaction mixture containing 11% CO, 43% H2, 6% CO2, 21% H2O (real feed composition mixture from the reformer) and balance He, with a reaction temperature range of 180–300 °C at a space velocity (SV) of 125,000 h−1. Catalyst supports (η-Al2O3 and γ-Al2O3), led to different synergetic effect between the two most active phases of Pt metal and Mo2C. Pt/Mo2C/η-Al2O3 is a promising catalyst (44% conversion at 180 °C) due to the close interaction between Pt and Mo2C phases on the surface of the catalyst. The 4 wt% Pt-Mo2C showed the highest activity where the temperature at which 50% conversion observed was at only 180 °C with SV of 125,000 h−1 and constant stability over 85 h.



中文翻译:

用于水煤气变换反应的高活性和协同作用的Pt / Mo 2 C / Al 2 O 3催化剂

自由Pt和Cu的催化剂支撑在沫2 C /η-Al系2 ö 3,MO 2 C /γ-Al系2 ö 3或Mo 2 C下制备并用于低温水煤气变换反应(WGSR)。通过元素分析,粉末X射线衍射(XRD),程序升温还原(TPR),X射线光电子能谱(XPS)和扫描电子显微镜(SEM)对催化剂进行了表征。该催化剂与含有11%CO,43%H的反应混合物的水煤气变换反应进行了研究2,6%CO 2,21%H 2O(来自重整炉的真实进料组成混合物)和He的平衡,在125,000 h -1的空速(SV)下反应温度范围为180–300°C 。催化剂载体(η-Al系2 ö 3和γ-Al系2 ö 3),导致了铂金属和Mo的两个最活跃相之间不同的协同效应2 C.的Pt /沫2 C /η-Al系2 ö 3是由于催化剂表面上的Pt和Mo 2 C相之间的紧密相互作用,是一种很有前途的催化剂(在180°C下转化率为44%)。4 wt%的Pt-Mo 2C表现出最高的活性,在该温度下观察到50%转化的温度仅为180°C,SV为125,000 h -1,并且在85 h内保持稳定。

更新日期:2018-05-29
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