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Lightweight chopped carbon fibre reinforced silica-phenolic resin aerogel nanocomposite: Facile preparation, properties and application to thermal protection
Composites Part A: Applied Science and Manufacturing ( IF 8.7 ) Pub Date : 2018-05-28 , DOI: 10.1016/j.compositesa.2018.05.026
Chonghai Wang , Haiming Cheng , Changqing Hong , Xinghong Zhang , Tao Zeng

A chopped carbon fibre (CF) reinforced silica-phenolic resin (Si/PR) aerogel nanocomposite was prepared through a simple one-pot sol-gel polymerization in a slurry of CF, PR, silane, hexamethylenetetramine and ethylene glycol. CFs were distributed homogeneously and randomly in the Si/PR aerogels. The Si/PR aerogels exhibit finer microstructure, higher thermal stability and better anti-oxidation resistance than PR aerogels. The compressive strength for the composites with low densities between 0.402 and 0.463 g/cm3 ranged from 0.33 to 2.44 MPa and thermal conductivities from 0.089 to 0.116 W/(mK), respectively. Furthermore, the CF/Si/PR aerogel nanocomposites could deliver linear ablation rates as low as 0.117 mm/s, and internal temperature peaks approximately 100 °C at 38 mm in-depth position as the surface temperature exceeded 1800 °C in oxyacetylene flame. From mentioned above, this lightweight composite presents huge application prospects in thermal protection and heat insulation field, especially in aerospace industry.



中文翻译:

轻质短切碳纤维增强二氧化硅-酚醛树脂气凝胶纳米复合材料:简便的制备,性能及其在热防护中的应用

通过在CF,PR,硅烷,六亚甲基四胺和乙二醇的浆液中进行简单的一锅式溶胶-凝胶聚合,制备了短切碳纤维(CF)增强的硅酚醛树脂(Si / PR)气凝胶纳米复合材料。CFs在Si / PR气凝胶中均匀且随机分布。Si / PR气凝胶比PR气凝胶具有更好的微观结构,更高的热稳定性和更好的抗氧化性。在0.402至0.463 g / cm 3之间的低密度复合材料的抗压强度范围从0.33到2.44 MPa,热导率从0.089到0.116 W /(mK)。此外,CF / Si / PR气凝胶纳米复合材料可提供低至0.117 mm / s的线性消融速率,并且在氧乙炔火焰中,当表面温度超过1800°C时,内部温度在38 mm深度处达到约100°C的峰值。综上所述,这种轻质复合材料在热防护和绝热领域,尤其是在航空航天工业中具有广阔的应用前景。

更新日期:2018-05-28
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