Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): a general protocol for the preparation of fluoroalkylthioesters†,Organic Chemistry Frontiers

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Radical fluoroalkylthiolation of aldehydes with PhSO2SRf (Rf = CF3, C2F5, CF2H or CH2F): a general protocol for the preparation of fluoroalkylthioesters†
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2018-05-28 00:00:00 , DOI: 10.1039/c8qo00327k
Bin Xu _{1,

2,

3,

4} , Dezhi Li _{5,

6,

7,

8,

9} , Long Lu _{4,

7,

9,

10} , Decai Wang _{1,

2,

3,

4} , Yonghong Hu _{1,

2,

3,

4} , Qilong Shen _{5,

6,

7,

8,

9}

Affiliation

A general method for the preparation of fluoroalkylthioesters including trifluoromethylthio/pentafluoroethylthio/difluoromethylthio/monofluoromethylthio-esters from aldehydes and a corresponding fluoroalkylthiolating reagent was reported. The reactions were conducted under mild conditions and various common functional groups such as fluorine, chloride, bromide, iodide, and ester groups were compatible.

中文翻译：

醛与PhSO ₂ SR _f（R _f = CF ₃，C ₂ F ₅，CF ₂ H或CH ₂ F）的自由基氟代烷基硫代烷基化：制备氟代烷基硫代酸酯的一般方案†

报道了由醛和相应的氟代烷基硫代化试剂制备氟代烷基硫代酸酯的通用方法，该方法包括三氟甲硫基/五氟乙硫基/二氟甲硫基/单氟甲硫基酯。该反应在温和的条件下进行，并且各种常见的官能团如氟，氯，溴，碘和酯基是相容的。

更新日期：2018-05-28

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