Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C–H bond activation at room temperature†,Chemical Communications

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Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C–H bond activation at room temperature†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-25 00:00:00 , DOI: 10.1039/c8cc03913e
G. Vlahopoulou _{1,

2,

3} , S. Möller _{1,

2,

3} , J. Haak _{1,

2,

3} , P. Hasche _{1,

2,

3} , H.-J. Drexler _{1,

2,

3} , D. Heller _{1,

2,

3} , T. Beweries _{1,

2,

3}

Affiliation

Rhodium(III) thiophosphinito pincer hydrido complexes were synthesised by C–H activation under exceptionally mild conditions at room temperature without additional base or irradiation and fully characterised by multinuclear NMR spectroscopy and X-ray crystallography. C–H activation under these mild conditions contrasts with the reactivity of related systems with POCOP ligands.

中文翻译：

室温下无碱CH键的活化合成Rh（iii）硫代膦酰钳式氢化物配合物†

铑（III）硫代膦酰钳式氢化物配合物是在室温下在异常温和的条件下通过C–H活化合成的，无需额外的碱或辐射，并通过多核NMR光谱学和X射线晶体学进行了全面表征。在这些温和条件下的C–H活化与相关系统与POCOP配体的反应性形成对比。

更新日期：2018-05-25

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