Nickel(II)-Catalyzed [8 + 3]-Cycloaddition of 2-Aryl-N-tosylaziridines with Tropone,Organic Letters

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Nickel(II)-Catalyzed [8 + 3]-Cycloaddition of 2-Aryl-N-tosylaziridines with Tropone
Organic Letters ( IF 5.2 ) Pub Date : 2018-05-24 00:00:00 , DOI: 10.1021/acs.orglett.8b01354
Honglei Liu ₁ , Hao Jia ₁ , Wangyu Shi ₁ , Chang Wang ₁ , Cheng Zhang ₁ , Hongchao Guo _{1,

2}

Affiliation

The Ni-catalyzed [8 + 3]-cycloaddition of tropone with 2-aryl-N-tosylaziridines proceeded smoothly under mild reaction conditions, affording various 4-tosyl-2,3,4,4a-tetrahydrocyclohepta[b][1,4]oxazine derivatives in moderate to excellent yields.

中文翻译：

镍（II）催化2-芳基-N-甲苯磺酰基氮丙啶与[tropone ]的[8 + 3]-环加成反应

Ni在2-芳基-N-甲苯磺酰基氮杂环丁烷上催化的[8 + 3]-环加氢萘酮在温和的反应条件下平稳进行，得到各种4-甲苯磺酰基-2,3,4,4a-四氢环庚[ b ] [1,4 ]恶嗪衍生物的产率中等至优异。

更新日期：2018-05-24

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