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Isoquinoline synthesis by C-H activation/annulation using vinyl acetate as an acetylene equivalent
Tetrahedron ( IF 2.1 ) Pub Date : 2018-05-25 , DOI: 10.1016/j.tet.2018.05.063
Nicola J. Webb , Steven A. Raw , Stephen P. Marsden

Vinyl acetate is used as an acetylene equivalent in rhodium(III)-catalysed C-H activation/annulation with aryl ketoxime esters. Extension to an aldoxime ester allows for a concise formal synthesis of decumbenine B.



中文翻译:

使用乙酸乙烯酯作为乙炔当量通过CH活化/环化合成异喹啉

乙酸乙烯酯用作铑(III)催化的芳基酮肟酯的CH活化/环化反应中的乙炔当量。延伸至醛肟肟酯可实现简明苯二酚B的简明形式合成。

更新日期:2018-05-25
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