Cp*Ir(iii)-catalyzed C–H/N–H functionalization of sulfoximines for the synthesis of 1,2-benzothiazines at room temperature†,Chemical Communications

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Cp*Ir(iii)-catalyzed C–H/N–H functionalization of sulfoximines for the synthesis of 1,2-benzothiazines at room temperature†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-23 00:00:00 , DOI: 10.1039/c8cc03288b
Yogesh N. Aher _{1,

2,

3,

4} , Dhanaji M. Lade _{1,

2,

3,

4,

5} , Amit B. Pawar _{1,

2,

3,

4,

5}

Affiliation

The first Cp*Ir(III)-catalyzed C–H/N–H bond functionalization of sulfoximines with α-diazocarbonyl compounds has been developed for the synthesis of 1,2-benzothiazines under redox-neutral conditions. The reactions proceed at room temperature with excellent functional group tolerance and high yields without the requirement of any silver additive.

中文翻译：

的Cp *铱（III）催化C-H /亚磺酰亚胺为1,2-苯并噻嗪在室温下将合成的N-H官能化†

已经开发出第一个由Cp * Ir（III）催化的亚砜基亚砜与α-重氮羰基化合物的C–H / N–H键官能团，用于在氧化还原中性条件下合成1,2-苯并噻嗪。反应在室温下以优异的官能团耐受性和高收率进行，不需要任何银添加剂。

更新日期：2018-05-23

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