当前位置: X-MOL 学术Polym. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Polymerization of acrylates based on n-type organic semiconductors using Cu(0)-RDRP†
Polymer Chemistry ( IF 4.6 ) Pub Date : 2018-05-18 00:00:00 , DOI: 10.1039/c8py00670a
Christopher M. Tonge 1, 2, 3, 4 , Ethan R. Sauvé 1, 2, 3, 4 , Nathan R. Paisley 1, 2, 3, 4 , Jordan E. Heyes 1, 2, 3, 4 , Zachary M. Hudson 1, 2, 3, 4
Affiliation  

Three acrylic monomers have been prepared based on organic semiconductor motifs commonly used as n-type materials in organic light-emitting diodes (OLEDs) and organic thin-film transistors (OTFTs). Facile room-temperature polymerizations were developed for these materials based on Cu(0) reversible deactivation radical polymerization (RDRP), providing polymers with polydispersities as low as 1.14 at conversions up to 97%. Under these conditions, these materials display first-order polymerization kinetics up to high conversions of 92–97%. The optical, electrochemical and thermal properties for each of these n-type materials are also described. These methods provide a simple and inexpensive route to well-defined polymeric n-type organic semiconductors with potential applications in organic electronic devices.

中文翻译:

使用Cu(0)-RDRP聚合基于n型有机半导体的丙烯酸酯

已经基于通常用作有机发光二极管(OLED)和有机薄膜晶体管(OTFT)中的n型材料的有机半导体图案制备了三种丙烯酸单体。基于Cu(0)可逆失活自由基聚合(RDRP)为这些材料开发了便利的室温聚合,可为聚合物提供高达97%的多分散度低至1.14的聚合物。在这些条件下,这些材料显示出高达92–97%的高转化率的一级聚合动力学。还描述了每种n型材料的光学,电化学和热学性质。这些方法提供了一种简单且廉价的途径,可用于定义明确的聚合物n型有机半导体,并有可能在有机电子设备中应用。
更新日期:2018-05-18
down
wechat
bug