New substituted 3-((1H-1,2,3-triazol-1-yl)methyl)-5-arylisoxazoles (aryl = Ph, p-Tol) and 2-(5-phenylisoxazol-3-yl)-5-(2-(1-((5-(p-tolyl)isoxazol-3-yl)methyl)-1H-1,2,3-triazol-4-yl)ethyl)-1,3,4-oxadiazole were synthesized by means of click-chemistry procedures. The obtained compounds were used as ligands in preparation of palladium(II) complexes, and the latter proved to be high-turnover-number catalysts for CC cross-coupling reactions under Green Chemistry conditions. One of the ligands was structurally characterized by single crystal X-ray diffraction, and the structure of complexes was determined by ¹H, ¹³C, ¹⁵N NMR spectroscopy and quantum-chemical modeling.

新的取代的3-（（（1H-1,2,3-三唑-1-基）甲基）-5-芳基异恶唑（芳基= Ph，对-Tol）和2-（5-苯基异恶唑-3-基）-5-合成了（2-（1-（（5-（对甲苯基）异恶唑-3-基）甲基）-1H-1,2,3-三唑-4-基）乙基）-1,3,4-恶二唑通过点击化学程序。所得化合物用作制备钯（II）配合物的配体，后者被证明是绿色化学条件下CC交叉偶联反应的高周转数催化剂。通过单晶X射线衍射在结构上表征配体之一，并通过¹ H，¹³ C，¹⁵ N NMR光谱和量子化学建模确定配合物的结构。