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Photochemistry for Well‐Defined Polymers in Aqueous Media: From Fundamentals to Polymer Nanoparticles to Bioconjugates
Macromolecular Rapid Communications ( IF 4.6 ) Pub Date : 2018-05-17 , DOI: 10.1002/marc.201800093
Kevin M. Burridge 1 , Thaiesha A. Wright 1 , Richard C. Page 1 , Dominik Konkolewicz 1
Affiliation  

This review article highlights recent developments in the field of photochemistry and photochemical reversible deactivation radical polymerization applied to aqueous polymerizations. Photochemistry is a topic of significant interest in the fields of organic, polymer, and materials chemistry because it allows challenging reactions to be performed under mild conditions. Aqueous polymerization is of significant interest because water is an environmentally benign solvent, and the use of water enables complex polymer self‐assembly and bioconjugation processes to occur. This review focuses on powerful new developments in photochemical aqueous polymerization reactions and their applications to the synthesis of well‐defined polymer nano‐objects and bioconjugates. It is anticipated that these aqueous photopolymerizations will enable the next generation of self‐assembled structures and biohybrid materials to be developed under mild and environmentally friendly conditions.

中文翻译:

水性介质中定义良好的聚合物的光化学:从基本原理到聚合物纳米颗粒再到生物结合物

这篇综述文章重点介绍了光化学和光化学可逆钝化自由基聚合应用于水性聚合领域的最新进展。光化学是有机化学,聚合物和材料化学领域中非常感兴趣的主题,因为它允许在温和条件下进行具有挑战性的反应。水性聚合具有重大意义,因为水是一种对环境无害的溶剂,而水的使用可使复杂的聚合物自组装和生物共轭过程发生。这篇综述集中在光化学水聚合反应的强大新进展及其在合成明确的聚合物纳米物体和生物共轭物方面的应用。
更新日期:2018-05-17
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