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Preparation of defective ZnFe2O4/graphene composites and their charge storage properties
Electrochemistry Communications ( IF 5.4 ) Pub Date : 2018-05-17 , DOI: 10.1016/j.elecom.2018.05.017
Shuhua Yang , Zhenzhen Han , Jing Sun , Xiaopeng Yang , Cuncheng Li , Rutao Wang , Bingqiang Cao

Defective ZnFe2O4/graphene (D-ZFO/G) composites are synthesized by a novel laser irradiation route. D-ZFO/G composites with unique architecture satisfy all the kinetic requirements for a desirable electrode material. Particularly, oxygen vacancies lied in D-ZFO/G provide abundant active sites for electrochemical reactions and enhance the intrinsic conductivity of ZFO for fast electron transport in D-ZFO/G electrode. D-ZFO/G composites then achieve a large specific charge of 474 C g−1 at 1 A g−1, high rate capability (95.8% at 10 A g−1), and excellent cycle life (98.9% capacity retention after 20,000 cycles).



中文翻译:

缺陷ZnFe 2 O 4 /石墨烯复合材料的制备及其电荷存储性能

ZnFe 2 O 4 /石墨烯(D-ZFO / G)复合材料是通过新颖的激光辐照途径合成的。具有独特结构的D-ZFO / G复合材料满足了所需电极材料的所有动力学要求。尤其是,D-ZFO / G电极中存在的氧空位为电化学反应提供了丰富的活性位点,并增强了ZFO的固有电导率,以便在D-ZFO / G电极中快速进行电子传输。然后,D-ZFO / G复合材料在1 A g -1下可获得474 C g -1的大比电荷,高倍率能力(在10 A g -1下为95.8%)和出色的循环寿命(20,000后的98.9%的容量保持率)周期)。

更新日期:2018-05-17
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