Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters†,Chemical Communications

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Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-16 00:00:00 , DOI: 10.1039/c8cc03121e
N. P. Martin _{1,

2,

3,

4,

5} , J. März _{6,

7,

8,

9} , H. Feuchter _{1,

2,

3,

4,

5} , S. Duval _{1,

2,

3,

4,

5} , P. Roussel _{1,

2,

3,

4,

5} , N. Henry _{1,

2,

3,

4,

5} , A. Ikeda-Ohno _{6,

7,

8,

9} , T. Loiseau _{1,

2,

3,

4,

5} , C. Volkringer _{1,

2,

3,

4,

5}

Affiliation

Successful synthesis of the first transuranium metal–organic frameworks (TRU-MOFs) involving tetravalent Np⁴⁺ is reported. These compounds were obtained from the controlled hydrolysis of Np⁴⁺ in the presence of dicarboxylate ligands. The final structures contain the [Np₆O₄(OH)₄(H₂O)₆]¹²⁺ unit, which were never crystallized before with tetravalent neptunium, associated with ditopic ligands.

中文翻译：

掺有{Np ₆ O ₈ }六核簇的第一个基于based的金属-有机骨架的合成和结构表征†

据报道，成功合成了涉及四价Np ⁴⁺的首个跨铀金属有机骨架（TRU-MOF）。这些化合物是在二羧酸盐配体存在下，由Np ⁴⁺的受控水解获得的。最终结构包含[Np ₆ O ₄（OH）₄（H ₂ O）₆ ] ¹²⁺单元，该单元从未与四价n结合，并与对位配体缔合。

更新日期：2018-05-16

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