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Room-Temperature C–H Functionalization Sequence under Benchtop Conditions for the Undergraduate Chemistry Laboratory
Journal of Chemical Education ( IF 3 ) Pub Date : 2018-05-09 00:00:00 , DOI: 10.1021/acs.jchemed.7b00694
Shuming Chen 1
Affiliation  

An iridium(III)-mediated C–H functionalization sequence involving a concerted cyclometalation–deprotonation/migratory insertion pathway is reported for the undergraduate chemistry laboratory. The air- and water-stable iridacycle intermediates are readily isolated and characterized by NMR spectroscopy. Both steps of the experiment are performed at room temperature under benchtop conditions, rendering the protocol suitable for a wide range of student skill levels.

中文翻译:

台式条件下本科化学实验室的室温C–H功能化序列

据报道,一个由铱(III)介导的C–H功能化序列涉及一个协同的环金属化-去质子化/迁移插入途径。空气和水稳定的iridacycle中间体很容易分离,并通过NMR光谱进行表征。实验的两个步骤均在室温,台式条件下进行,因此该方案适用于广泛的学生技能水平。
更新日期:2018-05-09
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