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Fabrication and characterization of multifunctional active food packaging from chitosan-titanium dioxide nanocomposite as ethylene scavenging and antimicrobial film
Food Hydrocolloids ( IF 10.7 ) Pub Date : 2018-05-03
Ubonrat Siripatrawan, Patinya Kaewklin

Active packaging with multifunctional properties from nanocomposite of chitosan and nanosized TiO2 to be used as ethylene scavenging and antimicrobial film was developed. Chitosan films containing different TiO2 concentrations (0, 0.25, 0.5, 1 and 2% w/w) were fabricated and characterized for structural, mechanical, optical and barrier properties. The scanning electron microscope images showed that TiO2 nanoparticles evenly distributed in the chitosan film matrix. However, the spontaneous agglomeration of the TiO2 was observed at high TiO2 concentration. The X–Ray diffraction patterns presented that crystallinity of TiO2 in the nanocomposite films increased with TiO2 concentration. The Fourier transform infrared spectra indicated that there were hydrogen bonding and O-Ti-O bonding between TiO2 and chitosan, which affected the tensile strength, elongation at break, and water vapor barrier properties of the films. The chitosan-TiO2 nanocomposites exhibited ethylene photodegradation which increased with increasing TiO2 concentration. Based on tensile strength, water barrier and ethylene photocatalytic degradation properties, chitosan film containing 1% TiO2 (CT1) was found to be optimal and, hence, was selected for antimicrobial evaluation. The results suggested that the CT1 exhibited antimicrobial activity against Gram-positive (Staphylococus aureus) and Gram-negative (Escherichia coli, Salmonella Typhimurium, and Pseudomonas aeruginosa) bacteria and fungi (Aspergillus and Penicillium).



中文翻译:

壳聚糖-二氧化钛纳米复合材料作为乙烯清除和抗菌膜的多功能活性食品包装的制备与表征

从壳聚糖和纳米TiO 2的纳米复合材料开发了具有多功能特性的活性包装,以用作乙烯清除和抗菌膜。制备了包含不同TiO 2浓度(0、0.25、0.5、1和2%w / w)的壳聚糖薄膜,并对其结构,机械,光学和阻挡性能进行了表征。扫描电子显微镜图像显示,TiO 2纳米颗粒均匀分布在壳聚糖膜基质中。然而,在高TiO 2浓度下观察到TiO 2的自发团聚。X射线衍射图案呈现的TiO该结晶2在纳米复合材料膜有TiO增加2专注。傅立叶变换红外光谱表明,TiO 2与壳聚糖之间存在氢键和O-Ti-O键,影响了薄膜的拉伸强度,断裂伸长率和水蒸气阻隔性能。壳聚糖-TiO 2纳米复合材料表现出乙烯光降解,其随TiO 2浓度增加而增加。基于抗张强度,阻水性和乙烯的光催化降解性能,发现含有1%TiO 2(CT1)的壳聚糖膜是最佳的,因此被选作抗菌评估。结果表明,CT1对革兰氏阳性(金黄色葡萄球菌)和革兰氏阴性(金黄色葡萄球菌)均具有抗菌活性。大肠杆菌鼠伤寒沙门氏菌和铜绿假单胞菌)和真菌(曲霉青霉菌)。

更新日期:2018-05-04
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