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h-BN@Copper(II) nanomaterial catalyzed cross-coupling reactions between sulfoximines and N-(phenylthio)-succinimide under mild condition
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-04-30
Yan Lin, L.Ü. Guanghui, Yanzhao Liu, Yang Zheng, Ruifang Nie, Li Guo, Yong Wu

A novel and efficient method for the synthesis of N

S substituted sulfoximines has been established with h-BN-supported copper(II) nanomaterial as the catalyst. Catalyzed by this heterogeneous catalyst, the desired products were obtained with wide scope of substrates, good to excellent yields, free ligand and low-toxicity solvent. Moreover, after being reused ten times, there is almost no significant loss of its catalytic activity.


中文翻译:

h- BN @ Copper(II)纳米材料在温和条件下催化亚砜与亚甲基N-(苯硫基)-琥珀酰亚胺的交叉偶联反应

一种新颖而有效的合成N的方法

h -BN负载的铜(II)纳米材料为催化剂,建立了S取代的亚砜亚胺。用这种非均相催化剂催化,可以得到所需产物,其底物范围宽,收率高至优异,游离配体和低毒性溶剂。而且,在重复使用十次之后,其催化活性几乎没有显着损失。
更新日期:2018-04-30
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