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Mulberry Paper‐Based Supercapacitor Exhibiting High Mechanical and Chemical Toughness for Large‐Scale Energy Storage Applications
Advanced Energy Materials ( IF 27.8 ) Pub Date : 2018-04-23 , DOI: 10.1002/aenm.201800064
Tae Gwang Yun 1, 2, 3 , Donghyuk Kim 1, 2, 3 , Sang-Min Kim 1 , Il-Doo Kim 2 , Seungmin Hyun 3 , Seung Min Han 1, 2
Affiliation  

In response to the demand for flexible and sustainable energy storage devices that exhibit high electrochemical performance, a supercapacitor system is fabricated using mulberry tree‐derived paper as a substrate and Poly(3,4‐ethylenedioxythiophene)‐poly(styrenesulfonate) (PEDOT:PSS) and carbon black as the active material. The mulberry paper‐based supercapacitor system demonstrates high energy density of 29.8–39.8 Wh kg−1 and power density of 2.8–13.9 kW kg−1 with 90.7% retention of its initial capacity over 15 000 charge–discharge cycles. In addition, the mulberry tree fibers are known to have superior mechanical strength and toughness and the mulberry paper‐based supercapacitor; as a result, exhibit high mechanical and chemical toughness; 99% of its initial capacity is retained after 100 repeated applications of bending strains, and twisting. 94% capacity retention is observed even after exposure to HCl and H2SO4 acid solutions. The fabrication methodology of the mulberry‐based supercapacitor is highly scalable and could be stacked to increase the energy storage capacity, where operation of light‐emitting diode lights with a drive voltage of 12 V integrated in a wearable device is demonstrated.

中文翻译:

桑树纸基超级电容器具有较高的机械和化学韧性,适用于大规模储能应用

为了满足对具有高电化学性能的灵活,可持续的储能设备的需求,超级电容器系统是使用桑树衍生的纸作为基材和聚(3,4-乙烯二氧噻吩)-聚(苯乙烯磺酸盐)(PEDOT:PSS)制成的。 )和炭黑作为活性物质。基于桑树纸的超级电容器系统显示出29.8–39.8 Wh kg -1的高能量密度和2.8–13.9 kW kg -1的功率密度在15 000次充放电循环中保留了90.7%的初始容量。此外,桑树纤维具有优异的机械强度和韧性,并具有桑树纸基超级电容器。结果显示出高的机械和化学韧性;经过100次反复施加弯曲应变和扭曲后,其初始容量的99%得以保留。即使暴露于HCl和H 2 SO 4酸性溶液中,也观察到94%的容量保持率。基于桑树的超级电容器的制造方法具有高度的可扩展性,可以堆叠起来以提高能量存储容量,其中展示了集成在可穿戴设备中的驱动电压为12 V的发光二极管灯的工作方式。
更新日期:2018-04-23
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