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Tunable Molecular‐Scale Materials for Catalyzing the Low‐Overpotential Electrochemical Conversion of CO2
Advanced Materials ( IF 29.4 ) Pub Date : 2018-04-25 , DOI: 10.1002/adma.201706238
Brian A. Rosen 1 , Idan Hod 2
Affiliation  

Electrochemical CO2 reduction provides a clean and viable alternative for mitigating the environmental aspects of global greenhouse gas emissions. To date, the simultaneous goals of CO2 reduction at high selectivity and activity have yet to be achieved. Here, the importance of engineering both sides of the electrode–electrolyte interface as a rational strategy for achieving this milestone is highlighted. An emphasis is placed on researchers contributing to the design of solid electrodes based on metal–organic frameworks (MOFs) and electrolytes based on room‐temperature ionic liquids (RTILs). Future research geared toward optimizing the electrode–electrolyte interface for efficient and selective CO2 reduction can be achieved by understanding the structure of newly designed RTILs at the electrified interface, as well as structure–activity relationships in highly tunable MOF platforms.

中文翻译:

可调谐的分子尺度材料,用于催化低电势的CO2电化学转化

减少电化学CO 2可以提供一种清洁可行的替代方法,以减轻全球温室气体排放的环境影响。迄今为止,还没有实现在高选择性和高活性下同时减少CO 2的目标。在此,强调了将电极-电解质界面的两侧进行工程设计作为实现此里程碑的合理策略的重要性。研究人员将重点放在为基于金属有机骨架(MOF)的固体电极和基于室温离子液体(RTIL)的电解质设计的研究上。未来研究旨在优化电极-电解质界面,以实现高效和选择性的CO 2 通过了解电气接口上新设计的RTIL的结构,以及高度可调的MOF平台中的结构-活动关系,可以减少这种情况。
更新日期:2018-04-25
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