当前位置: X-MOL 学术ChemPlusChem › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Transformation of Indium and Gallium Metal into Mixed Group 11/13 Ternary Sulfide Nanoparticles by Using a Dithioic Acid.
ChemPlusChem ( IF 3.4 ) Pub Date : 2018-05-14 , DOI: 10.1002/cplu.201800165
Dimuthu C Senevirathna 1 , Leone Spiccia 1 , Melissa V Werrett 1 , Philip C Andrews 1
Affiliation  

Heterobimetallic Group 11/13 sulfide nanoparticles (AgInS2 , CuInS2 , Ag9 GaS6 , and CuGaS2 ) are formed by treatment of [M(S2 CAr)3 ] (M=Ga or In) with either AgNO3 or CuCl under mild conditions. The intermediary gallium or indium tris(aryldithioate) complexes are easily prepared by stirring the appropriate metal and aryldithioc acid at room temperature. Overall, this two-step process is a simple solution-based method for transforming Ga and In metal into valuable ternary metallosulfide nanoparticles at relatively low temperatures.

中文翻译:

使用二硫代酸将铟和镓金属转变为11/13三元硫化物混合纳米颗粒。

通过在温和条件下用AgNO3或CuCl处理[M(S2 CAr)3](M = Ga或In)形成11/13杂双金属硫化物纳米粒子(AgInS2,CuInS2,Ag9 GaS6和CuGaS2)。通过在室温下搅拌适当的金属和芳基二硫辛酸,可以轻松地制备中间体三(芳基二硫代)镓或铟的配合物。总体而言,此两步过程是一种基于溶液的简单方法,可在相对较低的温度下将Ga和In金属转化为有价值的三元金属硫醚纳米颗粒。
更新日期:2018-05-14
down
wechat
bug