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Stability, mechanism and unique “zinc burning” inhibition synergistic effect of zinc dehydroacetate as thermal stabilizer for poly(vinyl chloride)
Polymer Degradation and Stability ( IF 5.9 ) Pub Date : 2018-04-20
Bozhen Wu, Yating Wang, Si Chen, Muyan Wang, Meng Ma, Yanqin Shi, Xu Wang

A novel kind of poly(vinyl chloride) (PVC) thermal stabilizer, zinc dehydroacetate (ZnL2), was designed and synthesized using zinc acetate and dehydroacetic acid (DA) as raw materials, which had a unique "zinc burning" inhibition synergistic effect with calcium stearate (CaSt2) that was 8 times greater than that of the CaSt2/ZnSt2 combination reference stabilizer. The structure and stability of ZnL2 were confirmed by Fourier-transform infrared, elemental analysis, and thermogravimetric analysis. The stability distinction of ZnL2 and ZnSt2, and the stable effect of the two systems after being combined with CaSt2, were investigated by the Congo red test, solution acidity test, and discoloration test. The results showed that in the Congo red test the stability time of ZnL2 was 8.9 min, which was 1.3 times that of ZnSt2, and the stability time of ZnL2/CaSt2 was 13 min, which was 1.4 times that of a traditional Ca/Zn stabilizer. Furthermore, the stability time of ZnL2 was 36 min in the solution acidity test, which was 2 times higher than that of ZnSt2, and the stability time was increased to 196 min after combining it with CaSt2, which was 8 times greater than that of the Ca/Zn stabilizer. Moreover, the dehydrochlorination rate of PVC stabilized with ZnL2 was slower than with other stabilizers. The system with ZnL2/CaSt2 could effectively delay “zinc burning” because of the excellent synergistic effect in the thermal aging test, with a stability time as long as 140 min. At the same time, the mechanism of PVC stabilization by ZnL2 was studied in two simple experiments, and the stabilization mechanism of ZnL2 in PVC degradation was speculated on.



中文翻译:

脱氢乙酸锌作为聚氯乙烯热稳定剂的稳定性,机理和独特的“烧锌”抑制协同作用

以乙酸锌和脱氢乙酸(DA)为原料,设计合成了一种新型的聚氯乙烯(PVC)热稳定剂脱氢乙酸锌(ZnL 2),具有独特的“烧锌”抑制协同作用。硬脂酸钙(CaSt 2)比CaSt 2 / ZnSt 2组合参考稳定剂的硬脂酸钙大8倍。ZnL 2的结构和稳定性通过傅立叶变换红外,元素分析和热重分析得到证实。ZnL 2和ZnSt 2的稳定性区别,以及与CaSt 2结合后两个体系的稳定作用通过刚果红试验,溶液酸度试验和变色试验进行了研究。结果表明,在刚果红试验中,ZnL 2的稳定时间为8.9 min,是ZnSt 2的1.3倍,ZnL 2 / CaSt 2的稳定时间为13 min,是传统的1.4倍。 Ca / Zn稳定剂。此外,溶液酸度测试中ZnL 2的稳定时间为36分钟,是ZnSt 2的2倍,与CaSt 2结合后的稳定时间增加到196 min ,是ZnSt 2的8倍。钙/锌稳定剂。此外,用ZnL 2稳定的PVC的脱氯化氢速率比其他稳定剂慢。ZnL 2 / CaSt 2的体系由于在热老化试验中具有出色的协同作用,因此可以有效地延迟“锌的燃烧”,其稳定时间长达140分钟。同时,通过两个简单的实验研究了ZnL 2稳定PVC的机理,并推测了ZnL 2稳定PVC降解的机理。

更新日期:2018-04-25
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