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Excitons in Single-Walled Carbon Nanotubes and Their Dynamics
Annual Review of Physical Chemistry ( IF 14.7 ) Pub Date : 2018-04-20 00:00:00 , DOI: 10.1146/annurev-physchem-050317-014241
Amanda R. Amori 1 , Zhentao Hou 1 , Todd D. Krauss 1, 2
Affiliation  

Understanding exciton dynamics in single-walled carbon nanotubes (SWCNTs) is essential to unlocking the many potential applications of these materials. This review summarizes recent progress in understanding exciton photophysics and, in particular, exciton dynamics in SWCNTs. We outline the basic physical and electronic properties of SWCNTs, as well as bright and dark transitions within the framework of a strongly bound one-dimensional excitonic model. We discuss the many facets of ultrafast carrier dynamics in SWCNTs, including both single-exciton states (bright and dark) and multiple-exciton states. Photophysical properties that directly relate to excitons and their dynamics, including exciton diffusion lengths, chemical and structural defects, environmental effects, and photoluminescence photon statistics as observed through photon antibunching measurements, are also discussed. Finally, we identify a few key areas for advancing further research in the field of SWCNT excitons and photonics.

中文翻译:


单壁碳纳米管中的激子及其动力学

了解单壁碳纳米管(SWCNT)中的激子动力学对于释放这些材料的许多潜在应用至关重要。这篇综述总结了在了解激子光物理,特别是SWCNT中激子动力学方面的最新进展。我们概述了SWCNT的基本物理和电子特性,以及在强约束一维激子模型框架内的明暗过渡。我们讨论了SWCNT中超快载流子动力学的许多方面,包括单激子状态(亮和暗)和多激子状态。与激子及其动力学直接相关的光物理性质,包括激子扩散长度,化学和结构缺陷,环境影响,还讨论了通过光子反聚束测量观察到的光致发光和光致发光的统计数据。最后,我们确定了一些关键领域,以推动SWCNT激子和光子学领域的进一步研究。

更新日期:2018-04-20
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