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Comments on the Artificiality of Actual Amount Adsorbed
Industrial & Engineering Chemistry Research ( IF 4.2 ) Pub Date : 2018-05-01 , DOI: 10.1021/acs.iecr.8b00852
Shivaji Sircar 1
Affiliation  

The artificiality of the actual amount adsorbed (AAA) estimated from the experimentally measured Gibbsian surface excess (GSE) of a gas is discussed. The use of AAA for calculation of isosteric heat of adsorption or mixed gas adsorption isotherms using ideal adsorbed solution theory can be misleading and incorrect. The GSE, on the other hand, can be unambiguously used to describe all practical aspects of adsorption science and technology.

中文翻译:

关于实际吸收金额的人工性的评论

讨论了根据气体的实验测量吉布斯表面过量(GSE)估算的实际吸附量(AAA)的人工性。根据理想的吸附溶液理论,使用AAA计算吸附的等构热或混合气体吸附等温线可能会引起误解和错误。另一方面,GSE可以明确地用于描述吸附科学和技术的所有实际方面。
更新日期:2018-05-01
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