Photophysical characterization of a highly luminescent divalent-europium-containing azacryptate†,Chemical Communications

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Photophysical characterization of a highly luminescent divalent-europium-containing azacryptate†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-04-17 00:00:00 , DOI: 10.1039/c8cc01737a
Tyler C. Jenks _{1,

2,

3,

4} , Matthew D. Bailey _{1,

2,

3,

4} , Brooke A. Corbin _{1,

2,

3,

4} , Akhila N. W. Kuda-Wedagedara _{1,

2,

3,

4} , Philip D. Martin _{1,

2,

3,

4,

5} , H. Bernhard Schlegel _{1,

2,

3,

4} , Federico A. Rabuffetti _{1,

2,

3,

4} , Matthew J. Allen _{1,

2,

3,

4}

Affiliation

We report a new luminescent Eu^II-containing complex. The complex is excited with visible light, leading to emission centered at 447 nm with a lifetime of 1.25 μs. Computational studies suggest that the steric bulk of the ligand is a major factor influencing the wavelength of emission.

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